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(12m(→σ(→p−q→A))2+qϕ)Ψ=iℏ∂tΨ
The Pauli equation describes how the state of a quantum system with half-integer spin changes in time.
In contrast, the Schrödinger equation describes the time evolution of systems without spin.
The Pauli equation is the non-relativistic limit of the Dirac equation.
The Pauli equation is the correct non-relativistic equation to describe spin 1/2 particles.
Take note that →σ, a "vector of matrices" is only used as a convenient short-hand notation for the sums that appear in the equation. For example, →σ→p=σ1p1+σ2p2+σ3p3.