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The Legendre transformation is a useful mathematical tool that is used in thermodynamics, classical mechanics and quantum field theory.
Maybe the most famous application is that in classical mechanics, quantum mechanics and quantum field theory the Hamiltonian and the Lagrangian are connected by a Legendre transformation.
Moreover, the Legendre transformation is used in thermodynamics to motivate the connection between the internal energy, enthalpy, and Gibbs and Helmholtz free energies.
Both uses can be compactly motivated if the Legendre transform is properly understood. Unfortunately, that transform is often relegated to a footnote in a textbook, or worse is presented as a complicated mathematical procedure. […] In a nutshell, a Legendre transform simply changes the independent variables in a function of two variables by application of the product rule.
https://www.aapt.org/docdirectory/meetingpresentations/SM14/Mungan-Poster.pdf
See: Making sense of the Legendre transform by R. K. P. ZiaEdward, F. RedishSusan, R. McKay
and Ryder - Quantum Field Theory page 260